Substrate for volatile delivery systems

ABSTRACT

Volatile impregnated substrates, such as wicks and mats, that can be used in a dispensing device that uses a heat source or otherwise uses active means to promote the release of the volatile material from the substrate are disclosed. The preferred substrate has a structure including sand particles adhered together by a binder to form a network of pores and passages. The binder is selected from thermoset polymeric materials and mixtures thereof. A volatile material is disposed in the pores before the substrate is installed in the dispensing device. The impregnated substrate is positioned in the dispensing device on or near the heat source of the dispensing device. The heat source is activated thereby elevating the temperature of the substrate such that volatile material is released from the pores. In one embodiment, the sand particles comprise silica sand and the binder is a cured novolac resin.

CROSS-REFERENCES TO RELATED APPLICATIONS

[0001] Not Applicable.

STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH

[0002] Not Applicable.

BACKGROUND OF THE INVENTION

[0003] 1. Field of the Invention

[0004] This invention relates to volatile dispensing devices that employactive means to dispense volatiles from a volatile-impregnatedsubstrate. More particularly, the invention relates to improved volatileimpregnated substrates, such as wicks and mats, that can be used in avolatile dispensing device that employs active means to dispense.

[0005] 2. Description of the Related Art

[0006] The following definitions apply herein: An “effective amount” oran “effective delivery rate” and the like term is defined to mean thatamount or rate sufficient to achieve the intended effect. “Active means”is defined as heat, moving air, or other means of imparting energy to avolatile material to be dispensed, and a volatile dispensing device thatemploys active means to dispense volatiles will be referred to as“actively dispensing” the volatile material. To be effective, insectcontrol volatile active ingredients have to be delivered at no less thanan “insect controlling rate,” defined herein as that rate sufficient torepel or otherwise control target insects within the space to beprotected.

[0007] Devices for dispensing thermally or otherwise volatilizablematerials into the atmosphere are well known. Such volatilizablematerials may be air scents (e.g. fragrances), pest control materials(e.g., insecticides), allergen control ingredients, disinfectants, andthe like.

[0008] In one type of volatile material dispensing device, a heat sourceis used to promote the wicking action and release of a volatile materialfrom a wick, one end of which is immersed in a volatile liquid containedin a reservoir. One version of this type of device is plugged into anelectrical wall outlet to supply power to a heating coil within ahousing. The generated heat raises the temperature of a materialcontained in the wick and volatilizes the material. Convection aircurrents dispense the volatilized material into the room. Examples ofthis type of device and related devices can be found in U.S. Pat. Nos.6,361,752; 5,647,053; 5,290,546; 5,222,186; 5,095,647; 5,038,394; and4,663,315. The disclosure of these patents and all other publicationsreferred to herein are incorporated herein by reference as if fully setforth.

[0009] In another type of volatile material dispensing device, a stiff,porous mat (commonly made of a pressed, cellulosic, fibrous material) isimpregnated with a volatile material, or a volatile material is placedin a pan-like metal structure. These mats and pans are then placed onheaters to cause the volatile material to vaporize into the atmosphere.One type of heater used for this purpose is sold by S.C. Johnson & Son,Inc. under the trademark “FUYI VAPE”. Examples of this type of deviceand related devices can be found in U.S. Pat. Nos. 6,446,384; 6,309,986;6,031,967; 5,945,094; and 4,391,781.

[0010] In yet another type of volatile material dispensing device, astiff, porous mat is impregnated with a volatile material, and the matis held within the device such that a flow of hot gases from a fuelburner passes over the mat and causes the volatile material to vaporizeinto the atmosphere. An example of this type of device can be found inPCT International Patent Publication No. WO 00/78135.

[0011] In yet another type of volatile material dispensing device,moving air is directed against a substrate or through a reticulated orotherwise airflow-transmitting substrate to thereby volatilize volatilematerial with the substrate has been impregnated. Examples of this typeof device can be found in U.S. Pat. No. 5,547,616 and in PCTInternational Patent Publication No. WO 01/02025.

[0012] While all of these devices provide satisfactory results undercertain circumstances, there are drawbacks to each type of device.

[0013] In devices that use a heat source to promote the release of avolatile material from a wick immersed in a volatile liquid composed ofsolvents and dissolved active ingredients, presently available wickingmaterials limit the performance of the wick of the device. For instance,when using porous wicks made of felt or fabric in such a device, thereis a tendency as the wick is heated for the solvents to quicklyvolatilize off, thereby leaving high boiling point materials behind inthe wick. The high boiling point materials remaining in the wick cancause clogging of the wick. Other wick materials include ceramics andcompressed sawdust. However, these wicks experience the same sort ofclogging when used in a device that uses a heat source to promote therelease of a volatile material from a wick immersed in a volatileliquid. As a result, it is difficult to maintain stable evaporation ofthe volatile liquid for extended time periods. While uniform release ofvolatiles has been reported in U.S. Pat. Nos. 4,286,754 for non-heatedwicks, the problem of non-linear release in heated wicks remains.

[0014] Certain volatile materials, such as some insecticideformulations, include materials that either are or become non-volatilewhen the liquid is heated in a wick. These non-volatile materials cancause clogging of the wick, which leads to a less uniform release rateof the volatile during use over time and to high residual levels ofnon-volatile materials in an expended wick. For example, pyrethruminsecticides typically include or form non-volatile waxes or polymers.During use in a dispenser having a conventional ceramic or sawdust wick,these waxes form sludges that can clog the wick. Thus, ceramic andsawdust wick systems do not allow effective utilization of insecticidalformulas that contain natural pyrethrins and terpenes.

[0015] One proposed solution to the problems associated with theclogging of wicks by non-volatiles formed by oxidation of pyrethruminsecticides has been the use of antioxidants in the liquid formulation.See, for example, U.S. Pat. No. 4,968,487. However, in spite ofantioxidants, some cross-linking of the isoprene units in insecticidalliquid formulations occurs, forming non-volatile components that degradethe wicking performance of traditional wicks. The performance losses inthese systems can be attributed to clogging of the small pores and theeffects of the high tortuosity (twists and turns) in conventional wickmaterials.

[0016] Certain disadvantages are also seen with devices that use a heatsource to promote the release of a volatile material from a solid orstiff porous mat impregnated with a volatile material or of a volatilematerial placed in a pan-like metal structure. One problem with themetal pan-like structures is that typical heaters can cause a volatilematerial to be exposed to too much heat. This can cause the volatile tobe used up too fast or be deteriorated or destroyed through thermaldegradation. Fibrous mats have similar but somewhat lesser problems inthis regard.

[0017] Dispensing devices using heated mats also have problems withrespect to the mats being exposed to differing temperatures across aheater surface. Existing heaters often have hotter regions at certainpoints along their heater surface, typically generally along a centerline. The mats therefore can have uneven and incomplete vaporization.Uneven mat heating can cause the overall rate at which insect controlvolatile active ingredients are delivered to drop below the insectcontrolling rate for the active while considerable quantities of theactive remain in poorly heated portions of the mat. Indeed, even asidefrom the issue of uneven heating, mats tend not to deliver a linearrelease of volatile materials. Commonly, the initial volatile deliveryrate is comparatively high, as active accessibly near the surface of themat quickly volatilizes. Once that accessible active is gone, migrationof active from the interior of the mat to the surface can be slow, atleast in part because of small, entrapping pores and very convolutedflow paths. The delivery rate decreases until the mat no longer deliversactive at an insect controlling rate and must be replaced. It is notuncommon that conventional insecticide mats for use with conventionalheaters have released only about 60% of their load of volatile materialbefore the delivery rate falls below an effective, insect controllingdelivery rate. This results in waste and therefore in increased cost forsuch mat products.

[0018] Another design consideration for insect control mats is thatexisting heaters often only accept slab-like inserts having a smallcross-sectional shape, necessary to fit into a small heater loading portor opening. Thus, any mat design preferably takes into account sizerestrictions imposed by existing heaters. Yet another critical designconsideration in this type of device is cost. Mats of this type areoften used in countries that have very modest average annual incomes. Tohave much practical application in those countries, the mats must beinexpensive.

[0019] Thus, there is a need for an improved liquid-delivery wick thatcan be used in a dispensing device that uses a heat source or otheractive means to promote the release of a volatile material from thewick. Furthermore, there is a need for an improved porous mat that canbe used in a dispensing device that-uses a heat source or other activemeans to promote the release of a volatile material from the mat. Inparticular, there is a need for wicks and porous mats that provideimproved efficacy (including but not limited to non-clogging, linear,and complete volatile release) and low cost, together with compatibilitywith existing dispensing devices.

BRIEF SUMMARY OF THE INVENTION

[0020] The foregoing needs are met by a substrate made according to theinvention for use in a volatile dispensing device that activelydispenses volatile material from the substrate. The substrate includesgranular particles adhered together to form a body having a network ofpores and passages, the interior surfaces of which are non-reactive andnon-absorptive with respect to the volatile material to be dispensed.The term “granular particles” is defined as meaning discrete,monolithic, compact particles (as distinct from linearly extendedparticles such as fiber strands or substantially continuous, porousmaterials such as ceramics) that, when packed in a confined space, havepoints of contact with neighboring particles but also leave open spacesbetween the particles. Sand particles are an example of such granularparticles and are preferred both for their low cost, ability towithstand heat, and non-reactivity. However, glass, high densitypolymeric particles, and other particles are also possible. Preferredhigh density polymers are high density polycarbonate and polyethylenepolymers. If the granular particles are non-organic, they can be adheredby any convenient means, including but not limited to point fusing byapplication of heat and/or pressure and/or the use of a polymerizing orother binder, coating, or the like that simply sticks the particlestogether, the latter means being preferred generally. However, if thegranular particles are made of an organic material, the substrate of theinvention is limited to particles adhered only by the use of apolymerizing or other binder, coating, or the like, without the use ofany sintering step. “Point fusing” is defined as fusing only at pointsof contact between neighboring particles without a substantial change inthe size and shape of the particles or the size and shape of the networkof passages and pores left between the particles.

[0021] A volatile material is disposed in the pores and passages.Activation of the volatile dispensing device releases the volatilematerial from the pores and passages, which volatile material is thendispensed. The volatile material may comprise an insect control activeingredient initially deliverable by the dispenser at an insectcontrolling rate, and preferably no more than 10% residual volatilematerial remains in the pores when the dispenser has so depleted thevolatile material as to no longer be able to deliver the volatilematerial at the insect controlling rate. When the substrate is used inan insecticide dispensing device, the volatile material is preferablyselected from natural pyrethrins, pyrethrum extract, syntheticpyrethroids, and mixtures thereof. When the substrate is used in an airtreating dispensing device, the volatile material can be a fragrance orother volatile air treatment material.

[0022] In another aspect of the invention, a substrate for a dispensingdevice that employs active means to promote release of a volatilematerial from the substrate includes a body including granular particlesadhered together by a binder to form a network of pores and passages.The binder is selected from cross-linked polymeric materials andmixtures thereof. In one preferred embodiment, the granular particlesare sand particles (and, even more preferred, sand particles thatinclude silica sand), and the binder is a cured phenolic resin such asnovolac resin, which is commercially available from many sources. Avolatile material is disposed in the pores, thereby impregnating thesubstrate, preferably before the substrate is installed in thedispensing device but also, optionally, after the substrate is locatedin or forms a permanent part of a device. In an example embodiment, thevolatile dispensing device has a slot through which the substrate can beinserted to load the substrate into the volatile dispensing device, andthe substrate is formed into a shape suitable for being suspended in theslot.

[0023] The substrate of the invention is positioned in the dispensingdevice so as to be subjected to the active means for dispensing volatilematerials. For example, for a dispensing device that uses heat as thatactive means, the substrate is positioned on or near the heat source ofthe dispensing device. In such a device, the heat source is activated,thereby elevating the temperature of the substrate such that volatilematerial is released from the pores. In a device employing air flow asthe active means, the substrate is so placed as to be exposed to the airflow.

[0024] In a preferred substrate of the invention, the pores occupy atleast 25% percent by volume of the substrate. It is also preferred thatthe pores have an average size in the range of 20 to 200 microns.

[0025] When using a substrate according to the invention in a heatedvolatile dispensing device, the volatile material is released from thepores at a substantially linear rate until release at an effective rateis no longer achieved. For example, if the volatile material is aninsect control active such as transfluthrin, the volatile material isreleased substantially linearly at an insect controlling rate until anend point is reached, after which very little volatile material remains.Advantageously, as little as 10% residual volatile material remains inthe pores after effective release of the volatile material from thesubstrate ceases, as evaluated and quantified by conventional gaschromatography and mass spectrometric methods. Even more preferred, nomore than 5% residual volatile material remains in the pores aftereffective release of the volatile material from the substrate ceases, asevaluated and quantified by conventional gas chromatography and massspectrometric methods.

[0026] When using a substrate according to the invention, many activeingredients can be used directly to impregnate the substrate, withouthaving to dilute the active ingredients with a solvent. For example, aninsect control mat of conventional size (approximately 3.5 by 2 cm.) canbe dosed with transfluthrin by depositing the desired amount of thatactive in liquid form and free of solvents, directly on the mat surface,whereupon it sinks promptly into the mat surface. In contrast,transfluthrin similarly deposited on a conventional, cellulosic matsinks into the mat so slowly as to be impractical for mass production ofdosed mats. Consequently, for conventional mats, the transfluthrin mustbe dissolved in a solvent to aid liquid migration before such mats canbe dosed.

[0027] The method of the invention for delivering a volatile materialfrom a dispensing device that uses a heat source to promote release ofvolatile materials from a wick designed to deliver a volatile liquidfrom a reservoir to a heated location within a heater wherein thevolatile liquid can be heated and volatilized, includes the followingsteps. First, one provides, as a replacement for a conventional wick or,alternatively, for both a conventional wick and reservoir, a substratehaving granular particles adhered together to form a body. The body hasa network of pores and passages, the interior surfaces of which arenon-reactive and non-absorptive with respect to the volatile material tobe dispensed, the body being so formed as to occupy the heated locationwithin the heater. A volatile material is disposed in the pores. Thesubstrate is placed within the dispensing device in the space normallyoccupied by a wick. Then the volatile dispensing device is activated torelease the volatile material from the pores, which volatile material isthen dispensed.

[0028] In another aspect of the invention, a method is provided fordispensing a volatile material from a heating device having (a) anenclosed heating chamber designed to hold the a volatile-impregnatedsubstrate therewithin, the heating chamber having chamber walls andbeing vented to the outside air; (b) a fuel burner; and (c) an air flowpath to guide hot gases generated by the fuel burner past the substrateto heat the substrate and release the volatile material therefrom. Themethod includes the steps of first providing a substrate holdable by theenclosed heating chamber, the substrate having granular particlesadhered together to form a body having a network of pores and passages,the interior surfaces of which are non-reactive and non-absorptive withrespect to the volatile material to be dispensed, the substrate alsohaving the volatile material to be dispensed, disposed in the pores. Thesubstrate is then installed in the heating chamber, and the fuel burneris activated to release the volatile material from the pores, whichvolatile material is then dispensed. In an example embodiment of thisaspect of the invention, the volatile material is a substance that isnon-liquid at a temperature of 30° C. or below, such as transfluthrin.

[0029] In yet another aspect of the invention, a method is provided fordispensing a volatile material from a dispensing device that uses a heatsource to promote release of volatile materials from a substrate byapplication of heat from a heating surface. The method includes thesteps of first providing a substrate of a size and shape selected to fitonto the heating surface, the substrate having granular particlesadhered together to form a body having a network of pores and passages,the interior surfaces of which are non-reactive and non-absorptive withrespect to the volatile-material to be dispensed. The substrate also hasthe volatile material to be dispensed, disposed in the pores. Then thesubstrate is installed on the heating surface, and the dispensing deviceis activated to cause the heating surface to heat to release thevolatile material from the pores, which volatile material is thendispensed. In an example embodiment of this aspect of the invention, thevolatile material is a substance that is non-liquid at a temperature of30° C. or below, such as transfluthrin.

[0030] In still another aspect of the invention, there is provided amethod for delivering a volatile material from a dispensing device thatuses a heat source to promote release of volatile materials from a wickdesigned to deliver a volatile liquid from a reservoir to a heatedlocation within a heater wherein the volatile liquid can be heated andvolatilized. First, one provides, as a volatile material in the liquidin the reservoir, an insect control active ingredient selected from thegroup consisting of natural pyrethrins, pyrethrum extract, syntheticpyrethroids, and mixtures thereof. Then, one provides, as a wick, asubstrate comprising granular particles adhered together to form a bodyhaving a network of pores and passages. The interior surfaces of thesubstrate are non-reactive and non-absorptive with respect to thevolatile material to be dispensed. The body is formed to occupy theheated location within the heater, and activation of the heat source ofthe volatile dispensing device releases the volatile material from thepores to dispense the volatile material. The construction of thesubstrate serves to limit clogging of the pores by the pyrethruminsecticides and/or associated waxes.

[0031] In still another aspect of the invention, a method for deliveringa volatile material from a dispensing device that uses a moving airstream to promote release of volatile materials from a substrate heldwithin the air stream includes the following steps. A substrate isprovided of a size and shape selected to be held in the air stream, thesubstrate having granular particles adhered together to form a bodyhaving a network of pores and passages, the interior surfaces of whichare non-reactive and non-absorptive with respect to the volatilematerial to be dispensed, the volatile material to be dispensed beingdisposed in the pores. The substrate is installed in the air stream, andthe dispensing device is activated to direct the air stream to thesubstrate to release the volatile material from the pores, whichvolatile material is then dispensed. When the volatile material is aninsect control active material it is preferred that the insect controlactive material be dispensed at an insect controlling rate until no morethan 10% or even 5% residual volatile material remains in the pores, andthat dispensing proceed at a substantially linear manner.

BRIEF DESCRIPTION OF THE DRAWINGS

[0032] These and other features, aspects, and advantages of the presentinvention will become better understood upon consideration of thefollowing detailed description, appended claims, and drawings where:

[0033]FIG. 1A is a perspective view showing a prior art device fordispensing volatile materials from a wick according to the invention.

[0034]FIG. 1B is a side cross-sectional view of the device of FIG. 1A.

[0035]FIG. 2 is a side cross-sectional view of an embodiment of a wickaccording to the invention being placed into the dispensing device ofFIGS. 1A and 1B.

[0036]FIG. 3 is a side cross-sectional view of an embodiment of a wickaccording to the invention installed in the dispensing device of FIGS.1A and 1B.

[0037]FIG. 4A is a perspective view showing another prior art device fordispensing volatile materials from another wick according to theinvention.

[0038]FIG. 4B is a side cross-sectional view of the device of FIG. 4A.

[0039]FIG. 5 is a side cross-sectional view of another embodiment ofanother wick according to the invention being placed into the dispensingdevice of FIGS. 4A and 4B.

[0040]FIG. 6 is a side cross-sectional view of another embodiment of awick according to the invention installed in the dispensing device ofFIGS. 4A and 4B.

[0041]FIG. 7 is a top, perspective view showing a prior art device fordispensing volatile materials from a porous mat according to theinvention.

[0042]FIG. 8 is a top perspective view of a porous mat according to theinvention.

[0043]FIG. 9 is a top perspective view of another porous mat accordingto the invention.

[0044]FIG. 10 is a side perspective view of another embodiment of aporous mat according to the invention installed in another prior artdispensing device.

[0045]FIG. 11 is a side perspective view of an embodiment of a porousplug according to the invention installed in the prior art dispensingdevice shown in FIG. 10.

[0046] Like reference numerals will be used to refer to like or similarparts from Figure to Figure in the following description of thedrawings.

DETAILED DESCRIPTION OF THE INVENTION

[0047] Referring to FIGS. 1A and 1B, there is shown a prior art heatedvolatile dispensing device 20 in which a heat source is used to promotethe wicking action and release of a volatile material from a wickimmersed in a volatile liquid contained in a reservoir. The dispensingdevice 20 includes a body 21 having a vapor outlet 24 formed in thecenter of the top of the body 21. A ring heater 25 having an openingextending vertically there through is provided inside the body 21 belowthe vapor outlet 24. The ring heater 25 is supported by a stay 26.Provided under the heater 25 is a bottle socket 27 having an openingextending vertically there through. The socket 27 is formed on its innerperiphery with a threaded portion 30 adapted for threaded engagementwith a threaded portion 29 on the outer periphery of the mouth 28 a of avolatile liquid bottle 28.

[0048] As shown in FIG. 1B, the bottle 28 is provided with a wick 31that is insertable into the ring heater 25 concentrically therewith whenthe bottle 28 is threaded at its mouth 28 a into the socket 27. The wick31 is immersed in the liquid 34 in the bottle 28 and upwardly transportsthe liquid 34 contained in the bottle 28 by capillary action. The wick31 is typically formed from a fired porous ceramic or a sintered plasticmaterial.

[0049] Electrical plug blades 32 in a pair are fixed to the body 21 onits rear side. The plug blades 32 are connected to the ring heater 25 inthe usual manner using electrical connections. The ring heater 25 isenergized by inserting the plug blades 32 into an electrical outlet andactivating switch 35 whereby the ring heater 25 produces heat to heatthe upper portion of the wick 31. The heat may promote upward transportof the liquid 34 in the wick 31. The liquid chemical 34 in the wick 31is vaporized by the heat from the ring heater 25. A more detaileddescription of this type of device can be found in U.S. Pat. No.5,290,546.

[0050] The wick 31 maybe simply made of the substrate of the invention,whereupon even solutions containing natural pyrethrums can be deliveredby the wick without the wick clogging, even over as much as forty-five,sixty, or more eight-hour nights, which are typical use expectations forinsect control products delivering insect control actives via a wick toa heater. Such a wick 31 may be cylindrical or any other convenientshape.

[0051] Turning now to FIGS. 2 and 3, the dispensing device 20 is shownwithout the bottle 28 and associated wick 31, which are replaced by aporous peg 70 according to the invention that is impregnated with avolatile material 22. The porous peg 70 includes an inverted truncatedcone shaped head 72 and a cylindrical body 74 that extends downwardlyfrom the head 72. The body 74 of the peg 70 is made small enough to beinserted from above into the hole 24 of the dispensing device 20, whilethe head 72 is made too wide to slip through the hole 24. The body 74 ofthe peg 70 is also made small enough to be insertable into the ringheater 25 concentrically therewith as shown in FIG. 3. The head 72 atthe top of the peg 70 is useful for handling, allowing a user to avoidtouching the volatile material 22, which is dosed only in the center (asshown in the cross-sectional view) or on the lower portion.

[0052] The porous peg 70 is inserted into the dispensing device 20 bymoving the peg 70 in the direction “A” shown in FIG. 2. The ring heater25 is then energized by inserting the plug blades 32 into an electricaloutlet and activating switch 35 whereby the ring heater 25 produces heatto heat the body 74 of the peg 70. The volatile material 22 in the peg70 is vaporized by the heat from the ring heater 25 and enters thesurrounding atmosphere. The materials used for the peg 70 and thepreparation of the peg 70 are described below.

[0053] Referring to FIGS. 4A and 4B, there is shown another prior artheated volatile dispensing device 20 a in which a heat source is used topromote the wicking action and release of a volatile material from awick immersed in a volatile liquid contained in a reservoir. Thedispensing device 20 a includes a body 21 having a vapor outlet 24 aformed in the center of the top of the body 21. The vapor outlet 24 aincludes inwardly projecting fingers 24 b which define a generallyrectangular opening 24 c. A ring heater 25 having an opening extendingvertically there through is provided inside the body 21 below the vaporoutlet 24. The heater 25 is supported by a stay 26. Provided under theheater-25 is a bottle socket 27 having an opening extending verticallythere through. The socket 27 is formed on its inner periphery with athreaded portion 30 adapted for threaded engagement with a threadedportion 29 on the outer periphery of the mouth 28 a of a volatile liquidbottle 28.

[0054] As shown in FIG. 4B, the bottle 28 is provided with a wick 31which is insertable into the ring heater 25 concentrically therewithwhen the bottle 28 is threaded at its mouth 28 a into the socket 27. Thewick 31 upwardly transports a liquid 34 contained in the bottle 28 bycapillary action. The wick 31 is typically formed from a fired, porousceramic or a sintered plastic material.

[0055] Electrical plug blades 32 in a pair are fixed to the body 21 onits rear side. The plug blades 32 are connected to the ring heater 25 inthe usual manner using electrical connections. The ring heater 25 isenergized by inserting the plug blades 32 into an electrical outlet andactivating switch 35 whereby the ring heater 25 produces heat to heatthe upper portion of the wick 31. The heat may promote upward transportof the liquid 34 in the wick 31. The liquid chemical in the wick 31 isvaporized by the heat from the ring heater 25. A more detaileddescription of this type of device can be found in U.S. Pat. No.5,290,546.

[0056] Turning now to FIGS. 5 and 6, the dispensing device 20 a is shownwithout the bottle 28 and associated wick 31, which are replaced byanother embodiment of a porous peg 80 according to the invention that isimpregnated with a volatile material. The porous peg 80 includes a diskshaped head 82 and a body 84 that extends downwardly from the head 82.The body 84 of the peg 80 is shown in a side view in FIG. 5. It can beseen that in a side view, the perimeter of the body 84 of the peg 80 hasan essentially rectangular shape. The body 84 of the peg 80 is shown ina front view in FIG. 6. It can be seen that in a front view, the body 84of the peg 80 includes a lower section 84 a having an essentiallyrectangular perimeter, a middle section 84 b having an essentiallyV-shaped perimeter, and an upper section 83 that extends from the middlesection 84 b to the head 82. With the peg 84 oriented as shown in FIG.5, the body 84 of the peg 80 is narrow enough to be inserted from aboveinto the rectangular opening 24 c of the dispensing device 20 a, whilethe head 82 is made too wide to slip through the rectangular opening 24c. The body 84 of the peg 80 is also made small enough to be insertableinto the ring heater 25 concentrically therewith as shown in FIG. 6.

[0057] The porous peg 80 is inserted into the dispensing device 20 a bymoving the peg 80 in the direction “B” shown in FIG. 5. The porous peg80 may then be rotated 90 degrees into a position as shown in FIG. 6.When the peg 80 is in this position, the inwardly projecting fingers 24b of the vapor outlet 24 a are positioned in grooves 83 a and 83 bbetween the middle section 84 b and the head 82 of the peg 80. The peg80 is thereby secured in the dispensing device 20 a until the peg isrotated 90 and lifted up and out of the dispensing device 20 a. Thus,the squared-off shank section of the shape shown fits into the existing,rectangular opening 24 c in the top of the heater, entering only whenturned to the correct position. Once in place, the peg can be turned,preventing its removal until turned again to its original position.After the peg 80 is inserted, the ring heater 25 is then energized byinserting the plug blades 32 into an electrical outlet and activatingswitch 35 whereby the ring heater 25 produces heat to heat the body 84of the peg 80. The volatile material in the peg 80 is then vaporized bythe heat from the ring heater 25 and enters the surrounding atmosphere.The materials used for the peg 80 and the preparation of the peg 80 aredescribed below.

[0058] Turning now to FIG. 7, there is shown a prior art volatilematerial dispensing device in which a solid porous mat impregnated witha volatile material is heated to release the volatile material. In FIG.7, there is shown an electrical heater, indicating generally at 40. Theheater is the “FUYI VAPE” heater previously described, except that themat previously used with that heater has been replaced with a mat 50 ofthe present invention. The heater 40 is an electrical resistance heater,and has a flat, upwardly exposed heating plate 42 on which is placed amat 50 of the present invention. An electrical plug 46 supplieselectricity to the heating plate 42 by means of an electrical cord 47.The heating plate 42 is energized by inserting the plug 46 into anelectrical outlet whereby the heating plate 42 produces heat to heat themat 50. The volatile material is vaporized by the heat from the heatingplate 42. The heating plate may be a ceramic or metal plate. This typeof device is described in more detail in U.S. Pat. No. 6,031,967.

[0059] Referring now to FIG. 8, there is shown one embodiment of a mat50 according to the invention. The mat 50 includes a body 52 and ahandle 54 extending outwardly from the body 52. The mat 50 is insertedinto the heater 40 by moving the mat 50 in the direction “C” shown inFIG. 7. The mat 50 then rests on the heating plate 42. The heater 40 isthen energized by inserting the plug 46 into an electrical outletwhereby the heating plate 42 produces heat to heat the body 52 of themat 50. The volatile material in the mat 50 is then vaporized by theheat from the heating plate 42 and is released from the surface 56 ofthe mat 50 thereby entering the surrounding atmosphere. The materialsused for the mat 50 and the preparation of the mat 50 are describedbelow.

[0060] Referring now to FIG. 9, there is shown another embodiment of amat 60 according to the invention. The mat 60 includes a body 62 and ahandle 64 extending outwardly from the body 62. The mat 60 is insertedinto the heater 40 by moving the mat 60 in the direction “C” shown inFIG. 7. The mat 60 then rests on the heating plate 42. The heater 40 isthen energized by inserting the plug 46 into an electrical outletwhereby the heating plate 42 produces heat to heat the body 62 of themat 60. The volatile material in the mat 60 is then vaporized by theheat from the heating plate 42 and is released from the surface 66 ofthe mat 60 thereby entering the surrounding atmosphere.

[0061] The mat 60 differs from the mat 50 in that the mat 60 has a firstregion 68 impregnated with a first volatile material and a second region69 impregnated with a second volatile material. The first region 68 andthe second region 69 provide the mat 60 with advantages, particularlywhen used in an insecticide delivery system. A typical heater as shownin FIG. 7 will have a warm up period in which the heating plate 42 rampsup to an operating temperature. By using two regions 68, 69 with twodifferent volatile materials such as two insecticides, insecticidedelivery can be tailored to the heating characteristics of the heatingplate 42. For example, the insecticide in the first region 68 may beselected to rapidly evaporate at the lower temperatures of the heatingplate warm up period, and the insecticide in the second region 69 may beselected to slowly evaporate at the steady operating temperature of theheating plate. As a result, the dispensing device 40 provides for aninitial burst of insecticide (from the first region 68) that clears thesurrounding atmosphere of insects and a steady slower release ofinsecticide (from the second region 69) that keeps the surroundingatmosphere free of insects. The fastest acting volatile materials can belocated where the heating plate surface heats the fastest (typically thecentral region of the heating plate). The materials used for the mat 60and the preparation of the mat 60 are described below.

[0062] In FIG. 10, there is shown a prior art volatile materialdispensing device in which a solid porous mat according to the inventionis used. The mat is impregnated with a volatile material, and is heatedto release the volatile material. The dispensing device 110 has a base112 that supports a removable chimney 114, the chimney attaching to thebase 112 with locking tabs formed on the lower edge of the chimney thatmate with locking slots 115 formed in the base 112. The chimney 114 canbe made of a heat resistant clear or translucent plastic. The base 112supports a candle cup 116 positioned centrally within the chimney 114.The candle cup 116 contains a wax candle. The base 112 has a base floor128 that has a central ventilation opening 129.

[0063] A ceiling 138 is positioned within the chimney 114 at its upperend. The ceiling 138 has ceiling vents 140 and an insert slot 142 thatcommunicate between the interior of the chimney 114 and the outside airabove the chimney. Hot gases flowing upwardly from the burning candle118 can escape the chimney 114 through the ceiling vents 140. The insertslot 142 is sized to receive a mat 144 according to the invention. Themat 144 includes a volatile bearing section 146 with laterally extendingears 148. The volatile bearing section 146 of the mat 144 is made smallenough to be inserted from above into the insert slot 142, while theears 148 are made too wide to slip through the insert slot 142. By thisarrangement, the volatile bearing section 146 can be suspended withinthe chimney 114, with the mat 144 hanging by the ears 148. A bafflestrip 150, made of a heat resistant material such as metal, is fastenedto the underside of the ceiling 138. The baffle strip 150 protects thedownwardly facing edge of the volatile bearing section 146 from thedirect impact of the hottest gases rising from the candle. In thedispensing device 110 of FIG. 10, heating is accomplished by the directexposure of the volatile bearing section 146 to gases from the candle.As the volatile bearing section 146 is heated by the gases, volatilematerial is released and is carried out of the dispensing device 110with the escaping hot gases. This type of device is described in moredetail in PCT International Patent Publication No. WO 00/78135.

[0064] In FIG. 11, there is shown a prior art volatile materialdispensing device 110 a in which another solid porous structureaccording to the invention is used. The solid porous structure isimpregnated with a volatile material, and is heated to release thevolatile material. The volatile material dispensing device 10 a of FIG.11 has the same features as the dispensing device 110 of FIG. 10 exceptthe mat 144 of the dispensing device 110 of FIG. 10 has been replaced bya porous plug 144 a in the dispensing device 1110 a of FIG. 11. Theporous plug 144 a is installed in a circular hole 188 in the ceiling 138a of the dispensing device 10 a. The porous plug 144 a includes a discshaped head 144 b and a cylindrical body 144 c that extends downwardlyfrom the head 144 b. The body 144 c of the plug 144 a is made smallenough to be inserted from above into the hole 188, while the head 144 bis made too wide to slip through the hole 188. By this arrangement, theporous plug 144 a can be suspended within the chimney 114, with the body144 c hanging by the head 144 b. In the dispensing device 110 a of FIG.11, heating is accomplished by the direct exposure of the porous plug144 a to gases from the candle. As the porous plug 144 a is heated bythe gases, volatile material is released and is carried out of thedispensing device 10 a with the escaping hot gases. The volatilematerial can be applied to the lower part of the plug 144 a so that auser, by handling only the head 144 b (the top-most part of the plug 144a) can avoid touching any volatile material.

[0065] Having described the arrangement of the peg 70 in the dispensingdevice 20 of FIGS. 1A, 1B, 2 and 3, the arrangement of the peg 80 in thedispensing device 20 a of FIGS. 4A, 4B, 5 and 6, the arrangement of themats 50 and 60 in the heater 40 of FIG. 7, the arrangement of the mat144 in the dispensing device 110 of FIG. 10, and the arrangement of theporous plug 144 a in the dispensing device 10 a of FIG. 11, a method forpreparing the peg 70, the peg 80, the mat 50, the mat 60, the mat 144,wicks made of the substrate of the invention, and the porous plug 144 acan be described.

[0066] The peg 70, the peg 80, the mat 50, the mat 60, the mat 144,wicks made of the substrate of the invention, and the porous plug 144 acomprise sand particles adhered together to form a network of pores andpassages. The particles are adhered together, preferably by a binder. Inone example method for making the peg 70, the peg 80, the mat 50, themat 60, the mat 144, or the porous plug 144 a, individual sand particlesare coated with a thin coating of the binder. The coated sand particlesare then placed in a mold and compacted under elevated temperatureconditions. The binder coated on the particles flows to form a thincoating on the individual particles, with the coatings fused together attheir points of contact. The binder only partially fills the intersticesbetween the particles, whereby an interconnected network of pores andpassages is formed.

[0067] The sand particles may comprise silica sand particles, chromitesand particles, zircon sand particles, and mixtures thereof. Silica sandparticles are typically preferred because a peg or mat formed usingsilica sand particles has superior fluid transport properties. Roundedparticles and preferably spherical particles are the best particlesbecause of the greater uniformity in porosity achieved and becauserounded particles can be closely packed together. The best uniformity inporosity is obtained by using particles that are uniform in size.

[0068] A number of different binders can be used to adhere the sandparticles together. Thermoset polymeric materials, i.e., materials thatbecome relatively infusible upon heating, are preferred for the binderbecause these cross-linking polymeric materials will not flow when theformed peg or mat is heated in the dispensing device. If the binder wereto flow excessively upon heating, clogging of the network of pores andpassages could result. However, as used herein, the term “thermosetpolymeric material” is not limited to traditional thermosettingmaterials but also encompasses cross linked thermoplastic materials thatchemically react to become relatively infusible upon heating. Thepreferred binder material is a novolac resin. Other non-limitingexamples of thermoset binder materials include urethane resins andhighly cross linked thermoplastics such as cross linked polyethylene.Furthermore, although thermoset polymeric materials are preferred, anypolymeric material can be used to bind the sand particles together, solong as the polymeric material is non-reactive and non-absorptive withrespect to the volatile material to be dispensed and the polymericmaterial can resist the temperatures to which the substrate will beexposed in the dispensing device. Such materials will be familiar tothose skilled in the art, including polymeric materials that set inresponse to various gas or other chemical or light treatment.

[0069] Because sand particles individually coated with the binder areflowable until adhered into a peg, mat, wick, or other shape, they maybe introduced into molds of various sizes and shapes and heated to formvirtually any shape structure for the peg 70, the peg 80, the mat 50,the mat 60, the mat 144, wicks made of the substrate of the invention,and the porous plug 144 a. Advantageously, the sand particles may bepurchased pre-coated. For example, resin coated sand particles areavailable from Technisand Division of Fairmount Minerals, Wedron, Ill.,USA. One type of commercially available resin coated sand comprises aphenol formaldehyde novolac resin (1-6% by total weight) and ahexamethylenetetramine curing agent (<2% by total weight) coated on anaggregate including iron oxides (<15% by total weight), aluminumsilicate (<15% by total weight) and silica sand (i.e., quartz). Anothertype of commercially available resin coated sand comprises a phenolformaldehyde novolac resin and a hexamethylenetetramine curing agentcoated on chromite sand. Yet another type of commercially availableresin coated sand comprises a phenol formaldehyde novolac resin and ahexamethylenetetramine curing agent coated on zircon sand.

[0070] In a most preferred embodiment, the peg 70, the peg 80, the mat50, the mat 60, the mat 144, wicks made of the substrate of theinvention, and the porous plug 144 a are formed from a novolac resincoated silica sand. The novolac resin coated silica sand is low pressureinjected into a heated mold at 300° F.-700° F. to form the peg 70, thepeg 80, the mat 50, the mat 60, the mat 144, wicks made of the substrateof the invention, and the porous plug 144 a. The mold heat completes theirreversible cross-linking of the novolac resin. Preferably, the networkof pores and passages formed occupies at least 25 to 30% by volumepercent of the peg 70, the peg 80, the mat 50, the mat 60, the mat 144,or the porous plug 144 a, and most preferably, the network of pores andpassages formed occupies at least 40% by volume percent of the peg 70,the peg 80, the mat 50, the mat 60, the mat 144, or the porous plug 144a. Preferably, the average pore size is in the range of 20 to 200microns, and most preferably, the average pore size is in the range of 4to 100 microns. In one form, the substrate has different densities atdifferent regions of the substrate.

[0071] In contrast to standard wicks used in liquid-electric volatiledispensing devices that have small pores and high tortuosity (twists andturns), the peg 70, the peg 80, the mat 50, the mat 60, the mat 144,wicks made of the substrate of the invention, and the porous plug 144 aaccording to the invention have lower tortuosity and larger pore sizewhile retaining adequate mass flow rate. The construction of the peg 70,the peg 80, the mat 50, the mat 60, the mat 144, wicks made of thesubstrate of the invention, and the porous plug 144 a incorporates apolymeric binder in order to reduce the contact angle of the fluid. Inaddition to the polymeric binder, polymeric surface coatings such asdimethyl silicone may be applied to the surfaces of the peg 70, the peg80, the mat 50, the mat 60, the mat 144, wicks made of the substrate ofthe invention, and the porous plug 144 a in order to further reduce thecontact angle and shield any slight imperfections and discontinuities inthe peg 70, the peg 80, the mat 50, the mat 60, the mat 144, wicks madeof the substrate of the invention, and the porous plug 144 a from thefluid where higher contact angles could result.

[0072] A volatile material is applied to the formed peg 70, peg 80, mat50, mat 60, mat 144, or porous plug 144 a to impregnate the pores withthe volatile material before the peg 70, peg 80, mat 50, mat 60, mat144, or porous plug 144 a are inserted into the dispensing device.Non-limiting examples of the thermally volatilizable materials includeair scents (e.g. fragrances), pest control materials (e.g., insecticidesor insect repellents), allergen control ingredients, disinfectants, andthe like. Optionally, the impregnated peg 70, peg 80, mat 50, mat 60,mat 144, or porous plug 144 a may be partially overmolded with plastic.

[0073] When the volatile material is an insecticide and/or insectrepellent, organic phosphorous insecticides, lipidamide insecticides,natural repellents as citronella oil, natural pyrethrins and pyrethrumextract, and synthetic pyrethroids are preferred. Suitable syntheticpyrethroids are acrinathrin, allethrin as D-allethrin, Pynamin®,benfluthrin, bifenthrin, bioallethrin as Pynamin Forte®, S-bioallethrin,esbiothrin, esbiol, bisoresmethrin, cycloprothrin, cyfluthrin,beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, cypermethrin,alpha-cypermethrin, beta-cypermethrin, cyphenothrin, deltamethrin,empenthrin, esfenvalerate, fenpropathrin, fenvalerate, flucythrinate,taufluvalinate, kadethrin, permethrin, phenothrin, prallethrin as Etoc®,resmethrin, tefluthrin, tetramethrin, tralomethrin, or transfluthrin.Other volatile insecticides as described in U.S. Pat. No. 4,439,415 canalso be employed.

[0074] When a substrate of the present invention is used for the purposeof delivering fragrance, various natural and artificial perfumes may beused. Non-limiting examples of these perfumes include animal-based andplant-based natural perfumes, and artificial perfumes such as alcohols,phenols, aldehydes, ketones, terpenes, and esters.

[0075] The choice of volatile material or mixtures of volatile materialsmay depend on the temperatures provided by the dispensing device. Forinstance, the heated volatile dispensing devices 20 and 20 a of FIGS. 1Aand 4A typically produce a wick surface temperature of about 100° C.when used with insecticides. Therefore, the volatile material or mixtureof volatile materials is selected to provide an efficient release of thevolatile materials from the peg 70 or the peg 80. Likewise, the heatedvolatile dispensing device 40 of FIG. 7 typically produces a mat surfacetemperature of about 140° C. to 170° C. when used with insecticides.Therefore, the volatile material or mixture of volatile materials isselected to provide an efficient release of the volatile materials fromthe mat 50 or the mat 60. The heated volatile dispensing devices 100 and110 a of FIGS. 10 and 11 typically produces a mat surface temperature ofabout 160° C. when used with insecticides. Therefore, the volatilematerial or mixture of volatile materials is selected to provide anefficient release of the volatile materials from the mat 144 or the peg144 a. Other optimum temperatures are used for air care products. Oneadvantage of a substrate according to the invention is that thesubstrate has heat transfer properties whereby heat may be applied atone end of the substrate and the substrate transfers heat such that thesubstrate has a substantially and effectively uniform temperaturethroughout the substrate when compared to conventional mats and wicks.Thus, a more uniform release of the volatile materials is possible fromall areas of the substrate. This is not possible with conventionalpolymeric, fibrous, or ceramic wicks that have insulating properties(see, for example, U.S. Pat. No. 3,652,197).

[0076] As detailed-above, the mat 60 of FIG. 9 has a first region-68impregnated with a first volatile material and a second region 69impregnated with a second volatile material. This arrangement of thefirst volatile material and the second volatile material is possiblebecause of the pore structures obtainable using the sand particles andbinder of the present invention. Specifically, the pore structureobtained using the sand or other non porous particles and a suitablebinder provides for very controlled migration of a volatile materialwhen the volatile material is applied to the formed mat 60. When a firstvolatile material is applied to the first region 68 of the mat 60, thefirst volatile material does not migrate into pores beyond the firstregion 68 of the mat 60. Likewise, when a second volatile material isapplied to the second region 69 of the mat 60, the second volatilematerial does not migrate into pores beyond the second region 69 of themat 60. As a result, the first volatile material and the second volatilematerial do not mix within the pores of the substrate. It should benoted that the mat 60 is not limited to just two regions and twovolatile materials, that is, any number of regions and volatilematerials is possible. The placement of different volatile materials indifferent regions of the mat 60 provides for tailored active materialsdelivery as described above with reference to faster acting and sloweracting volatile materials. The use of different types of volatilematerials is also possible. For example, use up indicators, such as acolored gel that co-evaporates independently of an insecticidalmaterial, a dye in the formula that co-evaporates, and multiple volatilematerials or actives (scents and insecticides), can provide an in-usecue and use-up cue.

[0077] A substrate (e.g., the peg 70, the peg 80, the mat 50, the mat60, the mat 144, wicks made of the substrate of the invention, and theporous plug 144 a) according to the invention has many advantages. Forexample, the sand based substrate provides fewer declines in dailydelivery rates from a dispensing device, and less clogging frompolymerized active materials (e.g., pyrethrum and limonene) in liquidwick applications. Volatile material migration is less with a substrateaccording to the invention versus conventional paper and ceramic wicksand mats thereby allowing for precise placement of different volatilematerials at different regions of the substrate. The substrate is alsohotter in the center than existing paper mats which is an advantage format products.

[0078] An example substrate-(e.g., the peg 70, the peg 80, the mat 50,the mat 60, the mat 144, wicks made of the substrate of the invention,and the porous plug 144 a) according to the invention having atransfluthrin insecticide is particularly advantageous. For instance,volatile material delivery is more linear in release over a longerinterval of time than other known products. This linear release can beachieved by either and both cycling on/off or running continuously,unlike other products that are not as linear no matter how they areused. Linear and super-extended volatile material delivery duration canbe achieved with a miniature sized part compared to other products onthe market. Higher heat conductivity and improved heat distributionallow for improved volatile release properties owing to homogeneousmaterial porosity and a pore structure that readily conducts heatthroughout and distant from the heat source. The superior thermalconductivity permits a wick to be used in conjunction with differenttemperature heaters or by adjusting the proximity of the wick to theheater to achieve any given desired temperature allowing for fast andslow volatile material release. The substrate readily retains puretransfluthrin in the pores resulting in less seeping or leaking, whilesimultaneously allowing it to completely release (no retention, noresidual) when heated. Therefore, less volatile material is required toachieve the same duration of other products due to the efficiency of thesystem not retaining volatile material. The substrate readily absorbspure transfluthrin into pores (quicker than ceramic or sawdust) withoutrequiring solvents, heat, or drying, achieving the elimination ofvolatile organic compounds (“VOC's”) emitted during the manufacturingoperation. Super extension of volatile release duration can be achievedwith no VOC's emitted during operation due to the elimination ofsolvents, performance uncommon to the industry standard that usessolvents to extend release. The substrate provides less clogging ofadditives that thermally degrade compared to ceramic or cellulosematerials. The substrate works with liquids with a reservoir or withoutliquids as the reservoir.

EXAMPLES

[0079] The following Examples are presented in order to furtherillustrate the invention. They are not intended to limit the inventionin any way.

Example 1

[0080] An insecticidal formulation suitable for impregnating the formedpeg 70 or peg 80 can be prepared by mixing the following ingredients inTable 1. The formed peg 70 or peg 80 of the present invention (which issuitable for use in electrically-heated liquid vaporizers) is compatiblewith the formulation of Table 1 which contains 1.2% Prallethrin, 1.25%pyrethrum, 2% butylated hydroxy toluene, 0.04% limonene and the balanceisoparaffin solvent. Until the present time, clogging problems intypical ceramic and sawdust wick systems did not allow utilization ofthis type of formula, which contains natural components like pyrethrinsand terpenes. TABLE 1 Weight Common name Percent of or commercialFunction in the Formulation name Chemical name formulation 94.36%Isopar-V isoparaffinic Solvent hydrocarbon 2.31% Kenya PyrethrumPyrethrin Conc. Insecticide Extract, 54% 54% 2.00% BHT, Technical 2,6di-t-butyl-p- Antioxidant cresol 1.29% ETOC (93%) Prallethrin 93%Insecticide 0.04% d-limonene d-limonene Fragrance

Example 2

[0081] Another insecticidal formulation suitable for impregnating theformed peg 70, peg 80 or mat 50 can be prepared by using the followingingredient in Table 2. Substrates can be dosed with transfluthrin bydepositing the desired amount of that active in liquid form and free ofsolvents, directly on the substrate surface, whereupon it sinks promptlyinto the surface. Transfluthrin is solid at room temperature but forms aliquid at about 32° C. Thus, liquid forms of transfluthrin can beobtained by heating solid transfluthrin to a temperature ofapproximately 32° C. or above. When loading a substrate according to theinvention with straight transfluthrin as in this Example and heating theloaded substrate with an approximately 70° C. heater, the transfluthrincomes off in a linear-manner and essentially all of the transfluthrincomes off the substrate. TABLE 2 Weight Percent Based on Total Weight ofPeg Common name or Chemical Function within the and Formula commercialname name formulation. 5.0% Transfluthrin Insecticide

Example 3

[0082] An insecticidal formulation suitable for impregnating the formedmat 50 can be prepared by mixing the following ingredients in Table 3.TABLE 3 Weight Percent of Common name or Chemical Function within theFormulation commercial name name formulation. 20% Isopar M IsoparaffinicSolvent Hydrocarbon 40% ETOC Prallethrin Insecticide 40% PiperonylButoxide Piperonyl Insecticide Butoxide

Example 4

[0083] An insecticidal formulation suitable for impregnating the mat 144or porous plug 144 a can be prepared by mixing the following ingredientsin Table 4. TABLE 4 Weight Percent Based on Total Weight of Peg Commonname or Function within and Formula commercial name Chemical name theformulation 23.75000 Pynamin Forte bioallethrin Insecticide 2.73000Yoshinox 425 Stabilizer 0.13000 C.I. Solvent Blue 35 Colorant CI 615540.17000 isopropyl myristate Solvent 9.08000 Isopar M IsoparaffinicSolvent Hydrocarbon 1.15000 ethyl alcohol Diluent 0.50000 Bitrexdenatonium Bittering Agent benzoate 62.49000 Mat or Plug Carrier

Example 5

[0084] A chemically-bonded sand wick was prepared by molding undercompaction at an elevated temperature of at least 300° F. a commerciallyavailable novolac resin coated silica sand available from TechnisandDivision of Fairmount Minerals, Wedron, Ill., USA. The chemically-bondedsand wick exhibited a very fast rate of imbibition relative to ceramicand sawdust types of absorbent wicks used in conventional heated liquidelectric dispensing devices. Electron micrographs showed a difference inpore size between the typical ceramic or sawdust wick and thechemically-bonded sand wick of the invention. When impregnated with theformula of Example 1, sawdust wicks in vaporizers showed a decline indelivery rate for the formula of Example 1 versus a control. Whenimpregnated with the formula of Example 1, the chemically bonded sandwick of this Example showed no substantial decline in delivery rate overtime for the test formula of Example 1 versus a control formula.

[0085] Thus, there has been provided improved volatile impregnatedsubstrates, such as wicks and mats, that can be used in a dispensingdevice that uses active means (such as a heat source or moving air) topromote the release of the volatile material from the substrate. Theinvention satisfies a need for volatile impregnated substrates thatprovide improved efficacy, safety, cost, compatibility with existingvolatile dispensing devices and environmental advantages.

[0086] In terms of improved efficacy, the volatile release rate (e.g.,mg./hr.) of a substrate according to the invention is more consistentover product life (e.g., intended use periods such as 8 hours, 12 hours,45 days, 60 days) compared to conventional wicks and mats; the releaserate duration can be extended beyond the product life of conventionalwicks and mats; and a more consistent release rate (e.g., mg./hr.) moretolerable of heater/candle temperature variability is possible. Thesubstrate does not burn (volatile materials with solvents may burn out);the substrate provides gritty texture surface that is considered adeterrent against child sucking; and the volatile material can stay incenter of the substrate, where placed, and migrates to heat, makingpossible handles that help prevent finger contact with volatilematerial.

[0087] In terms of cost, the substrate of the invention capitalizes onexisting dispensing devices in the market; the sand based mat costs arecomparable to a paper mat as many mats can be prepared in a single mold;the substrate can perform with or without the metal baffle strip 150shown in FIGS. 10 and 11; the substrate can eliminate the need for theplastic bottle, wick, insert and solvent formula of FIGS. 1B and 4B; andthe substrate can use volatiles that do not require solvents. Withrespect to compatibility, the substrate is conducive to cost-effectivedesigns for existing products with new shapes & textures (i.e., newlock-in key feature) and provides a longer lasting disposable productand a non-clogging refillable product. In terms of environmentaladvantages, the substrate is disposable with 96% natural organicelements, and has a low volatile residual, that is, the substrateempties to near zero milligrams of volatiles versus 30-60 milligrams ofvolatiles for existing wicks.

[0088] Although the present invention has been described in considerabledetail with reference to certain embodiments, one skilled in the artwill appreciate that the present invention can be practiced by otherthan the described embodiments, which have been presented for purposesof illustration and not of limitation. Therefore, the scope of theappended claims should not be limited to the description of theembodiments contained herein.

INDUSTRIAL APPLICABILITY

[0089] The invention relates to improved volatile material impregnatedsubstrates, such as wicks and mats, that can be used in a dispensingdevice that uses active means (such as a heat source or moving air) topromote the release of the volatile material from the substrate. Thevolatilizable materials may be air scents (e.g. fragrances), pestcontrol materials (e.g., insecticides), allergen control ingredients,disinfectants, and the like. Methods for making and using the inventionare disclosed.

1. A substrate for use in a volatile dispensing device that actively dispenses volatile material from the substrate, the substrate comprising: granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed; and a volatile material disposed in the pores, the volatile material comprising an insect control active ingredient initially deliverable by the dispenser at an insect controlling rate; wherein activation of the volatile dispensing device releases the volatile material from the pores, which volatile material is then dispensed, and wherein no more than 10% residual volatile material remains in the pores when the dispenser has so depleted the volatile material as to no longer be able to deliver the volatile material at the insect controlling rate.
 2. The substrate of claim 1 wherein the insect control active ingredient is selected from the group consisting of natural pyrethrins, pyrethrum extract, synthetic pyrethroids, and mixtures thereof.
 3. The substrate of claim 1 wherein the insect control active ingredient is selected from the group consisting of transfluthrin, bioallethrin, prallethrin, pyrethrum extract, and mixtures thereof.
 4. The substrate of claim 1 wherein the volatile material is essentially free of solvents when applied to the body.
 5. The substrate of claim 1 wherein the insect control active ingredient is transfluthrin.
 6. The substrate of claim 1 wherein the insect control active ingredient is released from the pores at a substantially linear rate when the volatile dispensing device releases the volatile material from the pores by heating the body.
 7. The substrate of claim 1 wherein the body includes a keying structure that engages a portion of the dispensing device to secure the body in the dispensing device.
 8. The substrate of claim 1 wherein the particles comprise sand.
 9. The substrate of claim 1 wherein the binder is a phenolic resin.
 10. The substrate of claim 1 wherein the dispenser supplies heat to a portion of the body less than the whole, and the body has heat transfer properties whereby heat applied to the portion of the body is transferred at a volatile-releasing rate to the remaining portions of the body.
 11. The substrate of claim 1 formed into a flat slab suitable for use as a mat for dispensing volatiles from a volatile dispensing device that delivers heat to volatile-bearing mats.
 12. A substrate for use in a volatile dispensing device that actively dispenses volatile material from the substrate, the volatile dispensing device having a slot through which the substrate can be inserted to load the substrate into the volatile dispensing device, the substrate comprising: granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed; and a volatile material disposed in the pores; wherein the substrate is formed into a shape suitable for being inserted in the slot, and wherein activation of the volatile dispensing device releases the volatile material from the pores, which volatile material is then dispensed.
 13. The substrate of claim 12 wherein the volatile material comprises an insect control active ingredient initially deliverable by the dispenser at an insect controlling rate.
 14. The substrate of claim 13 wherein no more than 10% residual volatile material remains in the pores when the dispenser has so depleted the volatile material as to no longer be able to deliver the volatile material at the insect controlling rate.
 15. The substrate of claim 12 wherein the volatile material comprises an insect control active ingredient selected from the group consisting of natural pyrethrins, pyrethrum extract, synthetic pyrethroids, and mixtures thereof.
 16. The substrate of claim 12 wherein the volatile material comprises an insect control active ingredient selected from the group consisting of transfluthrin, bioallethrin, prallethrin, pyrethrum extract, and mixtures thereof.
 17. The substrate of claim 12 wherein the volatile material is essentially free of solvents when applied to the body.
 18. The substrate of claim 17 wherein the volatile material comprises transfluthrin.
 19. The substrate of claim 12 wherein the insect control active ingredient is released from the pores at a substantially linear rate when the volatile dispensing device releases the volatile material from the pores by heating the body.
 20. The substrate of claim 12 wherein the body includes a keying structure that engages a portion of the dispensing device to secure the body in the dispensing device.
 21. The substrate of claim 12 wherein the substrate includes a first volatile material disposed in the pores in a first region of the body and a second volatile material disposed in the pores in a second region of the body.
 22. The substrate of claim 21 wherein the first volatile material vaporizes at a first temperature and the second volatile material vaporizes at a second temperature higher than the first temperature.
 23. The substrate of claim 21 wherein the first volatile material and the second volatile material do not mix within the pores of the substrate.
 24. The substrate of claim 12 wherein the dispenser supplies heat to a portion of the body less than the whole, and the body has heat transfer properties whereby heat applied to the portion of the body is transferred at a volatile-releasing rate to the remaining portions of the body.
 25. The substrate of claim 12 wherein the substrate has different pore sizes and porosities at different regions of the body.
 26. The substrate of claim 12 wherein the volatile material comprises a fragrance.
 27. The substrate of claim 12 wherein: the volatile material is released from the pores at an substantially linear rate until the action of the dispenser releases no more volatile material at an effective rate.
 28. A method for delivering a volatile material from a dispensing device that uses a heat source to promote release of volatile materials from a wick designed to deliver a volatile liquid from a reservoir to a heated location within a heater wherein the volatile liquid can be heated and volatilized, the method comprising the steps of: a. providing, as a replacement for the combination of a conventional wick and reservoir, a substrate comprising: i. granular particles adhered together to form a body shaped to occupy the heated location within the heater, the body having no access to a liquid reservoir and having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed, the body being formed to occupy the heated location within the heater; and ii. a volatile material disposed in the pores; iii. wherein activation of the volatile dispensing device releases the volatile material from the pores, which volatile material is then dispensed; and b. activating the heat source.
 29. The method of claim 28 wherein the volatile material is an insect control active material that is dispensed at an insect controlling rate until no more than 10% residual volatile material remains in the pores.
 30. A method for dispensing a volatile material from a heating device having an enclosed heating chamber designed to hold the a volatile-impregnated substrate therewithin, the heating chamber having chamber walls and being vented to the outside air; a fuel burner; and an air flow path to guide hot gases generated by the fuel burner past the substrate to heat the substrate and release the volatile material therefrom, the method comprising the steps of: a. providing a substrate holdable by the enclosed heating chamber, the substrate having: i. granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed; and ii. the volatile material to be dispensed, disposed in the pores; b. installing the substrate in the heating chamber; and c. activating the fuel burner to release the volatile material from the pores, which volatile material is then dispensed.
 31. The method of claim 30 wherein the volatile material is an insect control active material that is dispensed at an insect controlling rate until no more than 10% residual volatile material remains in the pores.
 32. The method of claim 30 wherein the volatile material is transfluthrin.
 33. A method for delivering a volatile-material from a dispensing device that uses a heat source to promote release of volatile materials from a substrate by application of heat from a heating surface, the method comprising the steps of: a. providing a substrate of a size and shape selected to fit onto the heating surface, the substrate having: i. granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed; and ii. the volatile material to be dispensed, disposed in the pores; b. installing the substrate on the heating surface; and c. activating the dispensing device to cause the heating surface to heat to release the volatile material from the pores, which volatile material is then dispensed.
 34. The method of claim 33 wherein the volatile material is an insect control active material that is dispensed at an insect controlling rate until no more than 10% residual volatile material remains in the pores.
 34. The method of claim 33 wherein the volatile material is transfluthrin.
 35. A method for delivering a volatile material from a dispensing device that uses a heat source to promote release of volatile materials from a wick designed to deliver a volatile liquid from a reservoir to a heated location within a heater wherein the volatile liquid can be heated and volatilized, the method comprising the steps of: a. providing, as a replacement for a conventional wick, a substrate comprising: i. granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed, the body being formed to occupy the heated location within the heater; and ii. a volatile material disposed in the pores; iii. wherein activation of the volatile dispensing device releases the volatile material from the pores, which volatile material is then dispensed; and b. activating the heat source.
 36. A method for delivering a volatile material from a dispensing device that uses a heat source to promote release of volatile materials from a wick designed to deliver a volatile liquid from a reservoir to a heated location within a heater wherein the volatile liquid can be heated and volatilized, the method comprising the steps of: a. providing as a volatile material in the liquid in the reservoir an insect control active ingredient selected from the group consisting of natural pyrethrins, pyrethrum extract, synthetic pyrethroids, and mixtures thereof; b. providing as a wick a substrate comprising granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed, the body being formed to occupy the heated location within the heater, wherein activation of the volatile dispensing device releases the volatile material from the pores, which volatile material is then dispensed; and c. activating the heat source.
 37. The method of claim 36 wherein the insect control active ingredient is selected from the group consisting of natural pyrethrins, pyrethrum extract, and mixtures thereof.
 38. A method for delivering a volatile material from a dispensing device that uses a moving air stream to promote release of volatile materials from a substrate held within the air stream, the method comprising the steps of: a. providing a substrate of a size and shape selected to be held in the air stream, the substrate having: i. granular particles adhered together to form a body having a network of pores and passages, the interior surfaces of which are non-reactive and non-absorptive with respect to the volatile material to be dispensed; and ii. the volatile material to be dispensed, disposed in the pores; b. installing the substrate in the air stream; and c. activating the dispensing device to direct the air stream to the substrate to release the volatile material from the pores, which volatile material is then dispensed.
 39. The method of claim 38 wherein the volatile material is an insect control active material that is dispensed at an insect controlling rate until no more than 10% residual volatile material remains in the pores. 